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Calculate The Ph At The Equivalence Point For The Titration Of 0.160 M Methylamine

Methylamine Equivalence Point pH Formula:

\[ pH = \frac{1}{2} pK_w + \frac{1}{2} pK_b + \frac{1}{2} \log(C) \]

(dimensionless)
(dimensionless)
mol/L

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1. What is the Methylamine Equivalence Point pH Calculation?

The calculation determines the pH at the equivalence point for the titration of methylamine, a weak base. At equivalence point, the solution contains the conjugate acid of methylamine, making the solution acidic.

2. How Does the Calculator Work?

The calculator uses the formula:

\[ pH = \frac{1}{2} pK_w + \frac{1}{2} pK_b + \frac{1}{2} \log(C) \]

Where:

Explanation: This formula calculates the pH at the equivalence point for weak base-strong acid titrations, where the solution contains the salt of the weak base.

3. Importance of pH Calculation at Equivalence Point

Details: Knowing the pH at equivalence point is crucial for selecting appropriate indicators in acid-base titrations and understanding the titration curve behavior.

4. Using the Calculator

Tips: Enter pKw (typically 14.00), pKb for methylamine (typically 3.36), and the concentration of methylamine solution. All values must be positive numbers.

5. Frequently Asked Questions (FAQ)

Q1: Why is the equivalence point pH not 7 for methylamine titration?
A: Methylamine is a weak base, so its salt with strong acid hydrolyzes to give an acidic solution at equivalence point.

Q2: What is the typical pKb value for methylamine?
A: The pKb for methylamine is typically 3.36 at 25°C.

Q3: How does temperature affect the calculation?
A: Temperature affects pKw value. pKw decreases with increasing temperature (13.99 at 37°C, 13.40 at 60°C).

Q4: Can this formula be used for other weak bases?
A: Yes, but you need to use the appropriate pKb value for the specific weak base being titrated.

Q5: What indicators are suitable for methylamine titration?
A: Indicators with transition ranges around the calculated pH (typically 5.5-6.5) such as methyl red are suitable.

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