pH Formula for Salt of Weak Acid and Weak Base:
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This calculator determines the pH of a solution formed from a salt of a weak acid and weak base. The pH depends on the relative strengths of the parent acid and base as represented by their dissociation constants.
The calculator uses the formula:
Where:
Explanation: The formula shows that the pH of such salt solutions depends on the relative strengths of the conjugate acid and base. When Ka = Kb, the solution is neutral (pH = 7).
Details: Calculating pH for salt solutions is important in understanding hydrolysis reactions, predicting solution properties, and designing buffer systems in chemical and biological applications.
Tips: Enter both Ka and Kb values in mol/L. The values must be positive numbers. The calculator will compute the pH based on the relationship between the acid and base strengths.
Q1: What does it mean when Ka = Kb?
A: When the acid and base dissociation constants are equal, the solution will be neutral with pH = 7, as the hydrolysis effects cancel each other out.
Q2: What happens when Kb > Ka?
A: When the base is stronger than the acid (Kb > Ka), the solution will be basic with pH > 7.
Q3: What happens when Ka > Kb?
A: When the acid is stronger than the base (Ka > Kb), the solution will be acidic with pH < 7.
Q4: Are there limitations to this formula?
A: This formula assumes ideal conditions and may need adjustment for very concentrated solutions or when additional ions are present that might affect the equilibrium.
Q5: How accurate is this calculation?
A: The calculation provides a good estimate for dilute solutions, but for precise work, experimental measurement or more complex calculations considering activity coefficients may be necessary.