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Calculating Ph From Ka And Kb

pH Formula for Salt of Weak Acid and Weak Base:

\[ pH = 7 + \frac{1}{2} \log\left(\frac{K_b}{K_a}\right) \]

mol/L
mol/L

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1. What is the pH Calculation for Salt of Weak Acid and Weak Base?

This calculator determines the pH of a solution formed from a salt of a weak acid and weak base. The pH depends on the relative strengths of the parent acid and base as represented by their dissociation constants.

2. How Does the Calculator Work?

The calculator uses the formula:

\[ pH = 7 + \frac{1}{2} \log\left(\frac{K_b}{K_a}\right) \]

Where:

Explanation: The formula shows that the pH of such salt solutions depends on the relative strengths of the conjugate acid and base. When Ka = Kb, the solution is neutral (pH = 7).

3. Importance of pH Calculation

Details: Calculating pH for salt solutions is important in understanding hydrolysis reactions, predicting solution properties, and designing buffer systems in chemical and biological applications.

4. Using the Calculator

Tips: Enter both Ka and Kb values in mol/L. The values must be positive numbers. The calculator will compute the pH based on the relationship between the acid and base strengths.

5. Frequently Asked Questions (FAQ)

Q1: What does it mean when Ka = Kb?
A: When the acid and base dissociation constants are equal, the solution will be neutral with pH = 7, as the hydrolysis effects cancel each other out.

Q2: What happens when Kb > Ka?
A: When the base is stronger than the acid (Kb > Ka), the solution will be basic with pH > 7.

Q3: What happens when Ka > Kb?
A: When the acid is stronger than the base (Ka > Kb), the solution will be acidic with pH < 7.

Q4: Are there limitations to this formula?
A: This formula assumes ideal conditions and may need adjustment for very concentrated solutions or when additional ions are present that might affect the equilibrium.

Q5: How accurate is this calculation?
A: The calculation provides a good estimate for dilute solutions, but for precise work, experimental measurement or more complex calculations considering activity coefficients may be necessary.

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