pH and pOH Equations:
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pH and pOH are logarithmic measures of the acidity and basicity of aqueous solutions. pH represents the negative logarithm of hydrogen ion concentration, while pOH represents the negative logarithm of hydroxide ion concentration. Their sum always equals 14 at 25°C.
The calculator uses the fundamental pH equations:
Where:
Explanation: These equations allow interconversion between hydrogen ion concentration, hydroxide ion concentration, pH, and pOH values for aqueous solutions at 25°C.
Details: Accurate pH and pOH calculations are essential in chemistry, biology, environmental science, and industrial processes. They help determine solution acidity/basicity, predict chemical behavior, and maintain optimal conditions for biological systems.
Tips: Enter any one known value (H⁺ concentration, OH⁻ concentration, pH, or pOH) and the calculator will compute the other three values. All concentrations should be in mol/L, and pH/pOH values should be between 0-14.
Q1: What is the relationship between pH and pOH?
A: pH + pOH = 14 for aqueous solutions at 25°C. This relationship comes from the ion product of water (K_w = [H⁺][OH⁻] = 1.0 × 10⁻¹⁴).
Q2: What are typical pH values for common substances?
A: Battery acid: pH ~0, Lemon juice: pH ~2, Pure water: pH 7, Baking soda: pH ~9, Ammonia: pH ~11, Drain cleaner: pH ~14.
Q3: How does temperature affect pH calculations?
A: The pH + pOH relationship changes with temperature because K_w changes. At 25°C, K_w = 1.0 × 10⁻¹⁴, but this value increases with temperature.
Q4: What is the significance of logarithmic scales?
A: Logarithmic scales allow representation of very small concentrations (10⁻¹ to 10⁻¹⁴ M) on a manageable 0-14 scale, where each unit change represents a tenfold change in concentration.
Q5: Are there limitations to these calculations?
A: These equations assume ideal behavior and 25°C temperature. For very concentrated solutions or non-aqueous solvents, additional factors must be considered.