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Formula For Calculating Ph Of Weak Base

Weak Base pH Formula:

\[ pOH = -\log \sqrt{K_b \times C} \] \[ pH = 14 - pOH \]

mol/L
mol/L

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1. What Is The Weak Base pH Formula?

The weak base pH formula calculates the pH of a weak base solution using the approximation method. It estimates pH based on the base dissociation constant (Kb) and concentration (C) of the weak base.

2. How Does The Calculator Work?

The calculator uses the weak base approximation formula:

\[ pOH = -\log \sqrt{K_b \times C} \] \[ pH = 14 - pOH \]

Where:

Explanation: This approximation assumes that the weak base is only partially dissociated and that the concentration of hydroxide ions comes primarily from this dissociation.

3. Importance Of pH Calculation For Weak Bases

Details: Accurate pH calculation is crucial for understanding chemical reactions, buffer solutions, and biological systems where weak bases play important roles.

4. Using The Calculator

Tips: Enter the base dissociation constant (Kb) in mol/L and concentration (C) in mol/L. Both values must be positive numbers greater than zero.

5. Frequently Asked Questions (FAQ)

Q1: When is this approximation valid?
A: This approximation works best when Kb is small (typically < 10⁻³) and concentration is not too dilute.

Q2: What are typical Kb values for weak bases?
A: Weak bases typically have Kb values between 10⁻² and 10⁻¹² mol/L, with ammonia (Kb = 1.8 × 10⁻⁵) being a common example.

Q3: When should I use the exact method instead?
A: Use the exact quadratic or iterative method when the approximation fails, typically when the base is relatively strong or very dilute.

Q4: How does temperature affect the calculation?
A: Temperature affects both Kb and Kw (water dissociation constant), so values should be specified at a particular temperature (usually 25°C).

Q5: Can this formula be used for polyprotic bases?
A: For polyprotic bases, the calculation is more complex and typically only the first dissociation is considered for weak polyprotic bases.

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