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Weak Base pH Equation:

\[ pH = 14 - \frac{1}{2} pKb - \frac{1}{2} \log C \]

dimensionless
mol/L

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1. What is the Weak Base pH Equation?

The weak base pH equation calculates the pH of a solution containing a weak base using its pKb value and concentration. This equation provides an approximation of the pH for weak base solutions.

2. How Does the Calculator Work?

The calculator uses the weak base pH equation:

\[ pH = 14 - \frac{1}{2} pKb - \frac{1}{2} \log C \]

Where:

Explanation: This equation is derived from the equilibrium expression for weak bases and provides a simplified method to estimate pH.

3. Importance of pH Calculation for Weak Bases

Details: Accurate pH calculation is crucial for understanding the behavior of weak base solutions, predicting chemical reactivity, and applications in various chemical and biological processes.

4. Using the Calculator

Tips: Enter pKb value (dimensionless) and concentration in mol/L. Both values must be valid (pKb ≥ 0, concentration > 0).

5. Frequently Asked Questions (FAQ)

Q1: What is the range of validity for this equation?
A: This equation provides a good approximation for dilute solutions of weak bases where the concentration is significantly greater than the hydroxide ion concentration.

Q2: How does pKb relate to base strength?
A: Lower pKb values indicate stronger bases, while higher pKb values indicate weaker bases.

Q3: When is this equation not appropriate?
A: This equation may not be accurate for very concentrated solutions, very strong bases, or when dealing with polyprotic bases.

Q4: How does temperature affect the calculation?
A: Temperature can affect both pKb values and the autoprotolysis constant of water, which may require adjustments for precise calculations.

Q5: Can this be used for buffer solutions?
A: For buffer solutions containing weak bases and their conjugate acids, the Henderson-Hasselbalch equation should be used instead.

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