pH Calculation Formula:
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pH calculation from hydroxide ion concentration [OH⁻] is a fundamental concept in acid-base chemistry. The pH scale measures the acidity or basicity of a solution, with values below 7 indicating acidity, 7 being neutral, and values above 7 indicating basicity.
The calculator uses the formula:
Where:
Explanation: This formula converts hydroxide ion concentration to pH value using the relationship between pH and pOH (pH + pOH = 14).
Details: Accurate pH calculation is essential for various chemical processes, biological systems, environmental monitoring, and industrial applications where pH control is critical.
Tips: Enter hydroxide ion concentration in mol/L. The value must be positive and greater than zero for valid calculation.
Q1: Why is the formula pH = 14 + log[OH⁻]?
A: This formula is derived from the relationship pH + pOH = 14, where pOH = -log[OH⁻], so pH = 14 - (-log[OH⁻]) = 14 + log[OH⁻].
Q2: What is the valid range for [OH⁻] concentration?
A: The concentration should be between 10⁻¹⁴ mol/L and 1 mol/L for aqueous solutions at 25°C, corresponding to pH values between 0 and 14.
Q3: How accurate is this calculation?
A: The calculation provides theoretical pH values. In real solutions, activity coefficients and temperature effects may cause slight variations.
Q4: Can this calculator be used for very concentrated solutions?
A: For highly concentrated solutions (>1M), the calculation may be less accurate due to ionic strength effects and deviation from ideal behavior.
Q5: What about temperature effects?
A: The relationship pH + pOH = 14 is valid at 25°C. At other temperatures, the sum changes (e.g., 13.99 at 0°C, 13.62 at 100°C).