Henderson-Hasselbalch Equation:
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The Henderson-Hasselbalch equation is used to estimate the pH of buffer solutions. It relates pH, pKa (acid dissociation constant), and the ratio of the concentrations of the conjugate base and weak acid in the buffer system.
The calculator uses the Henderson-Hasselbalch equation:
Where:
Explanation: The equation shows that pH depends on the pKa of the acid and the ratio of base to acid concentrations in the buffer system.
Details: Accurate pH calculation is crucial for maintaining proper water chemistry in swimming pools. Buffer systems like borate or carbonate help stabilize pH levels, preventing rapid pH changes and ensuring comfortable swimming conditions while protecting pool equipment.
Tips: Enter pKa value, base concentration in mol/L, and acid concentration in mol/L. All values must be valid (pKa > 0, base ≥ 0, acid > 0).
Q1: What are common buffer systems used in pools?
A: Common pool buffer systems include carbonate (carbonic acid/bicarbonate) and borate (boric acid/borate) systems.
Q2: What is the ideal pH range for swimming pools?
A: The ideal pH range for swimming pools is typically 7.2-7.8 to ensure swimmer comfort and effective chlorine disinfection.
Q3: How does temperature affect pH calculations?
A: Temperature can affect pKa values and should be considered for precise calculations, though the effect is often small for pool applications.
Q4: Why is buffer capacity important?
A: Buffer capacity determines how well the system resists pH changes when acids or bases are added to the water.
Q5: Can this calculator be used for other buffer systems?
A: Yes, the Henderson-Hasselbalch equation applies to any acid-base buffer system, though pKa values will differ.